A New Example of a Palladium-Assisted Aryl Rearrangement. Synthesis and Reactivity of (2,3,4-Trimethoxy-6-X-phenyl)palladium [X = CHO, CHN(n-C10H21), CHNC6H4(NH2)-2, C(O)Me] and (3,4,5-Trimethoxy-2-X-phenyl)palladium [X = CHO, CH=NC6H4(NH2)-2] Complexes. Crystal and Molecular Structure of [Pd(κ3-C6H{CHNC6H4(NH2)-2}-6-(OMe)3-2,3,4)(PPh3)]CF3SO3, [Pd(κ3-C6H{CHNC6H4(NH2)-2}-2-(OMe)3-3,4,5)(PPh3)]CF3SO3, and [Pd(κ2-C6H{C(O)Me}-6-(OMe)3-2,3,4)(2,9-dimethyl-1,10-phenanthroline)]CF3SO3

1. Vicente, J.
2. Abad, J.-A.
3. Gil-Rubio, J.
4. Jones, P.G.
5. Bembenek, E.